Pure, crystalline solids have a characteristic melting point, the temperature at which the solid melts to become a liquid.The transition between the solid and the liquid is so sharp for small samples of a pure substance that melting points can be measured to 0.1 o C. The melting point of solid oxygen, for example, is -218.4 o C. [15] The compound was registered for use as a preplant soil treatment for field grown strawberries, peppers, tomatoes, grape vines, ornamentals and turf and nursery grown strawberries, stone fruits, tree nuts, and conifer trees. NOAA: CAMEO Chemicals - It has a tetrahedral shape and it is a recognized ozone-depleting chemical. Merck & Co., Whitehouse Station, New Jersey. %
Tina's is 149C - 154 C. Jeff . For example, the melting point of ice (frozen water) is 0 C. Value ControlparametersBasisMethyl iodide 74-88-4 TWA 2.000000 ppmUSA. 806064. 1985. Continue rinsing. It has the chemical formula CH3I, sometimes written as MeI . ; Flanagan, R.J., Detection and Identification of Volatile Organic Compounds in Blood by Headspace Gas Chromatography as an Aid to the Diagnosis of Solvent Abuse, J. (Draize Test)Serious eye damage/eye irritationEyes - RabbitResult: Risk of serious damage to eyes. of St. Petersburg Univ. Povidone-iodine ointment demonstrates in vitro efficacy against biofilm formation. Iodomethane is formed via the exothermic reaction that occurs when iodine is added to a mixture of methanol with red phosphorus. Iodomethane is routinely and regularly used in industrial processes as well as in most university and college chemistry departments for study and learning related to a variety of organic chemical reactions. Chromatogr., 437, 1988, 33-45. umn class: Standard polar; Column length: 2 m; Column type: Packed; Start T: 100 C; CAS no: 74884; Active phase: Carbowax 20M; Data type: Kovats RI; Authors: Rohrschneider, L., Eine methode zur charakterisierung von gaschromatographischen trennflussigkeiten, J. Evacuate personnelto safe areas.For personal protection see section 8.6.2 Environmental precautionsPrevent further leakage or spillage if safe to do so. The Montreal protocol on substances that deplete the ozone layer. Purity 99%. The name Iodine is derived from the Greek word "iodes" meaning violet. A second-order cidnp spectrum." 1; Resp. In this case, a student reacted 40 drops of an unknown amine with 20 drops of iodomethane in 2 ml of a suitable solvent mixture. Plant Dis. The melting point is also referred to as liquefaction point, solidus, or liquidus. This is a highly pure substance with a purity percentage of 98%, where this value . The light changed to red. 52875-4, Department of Pesticide Regulation, Registration Branch, Sacramento, California. Bodewitz, H. W. J. J., et al. <>
Iodomethane may also be prepared by treating iodoform with potassium hydroxide and dimethyl sulfate under 95% ethanol.[7]. Like many organoiodide compounds, iodomethane is typically stored in dark bottles to inhibit degradation caused by light to give iodine, giving degraded samples a purplish tinge. Solve "Chemical Bonding Study Guide" PDF, question bank 6 to review worksheet: Chemical bonding types, chemical bonding electron pair, bond angle, bond energy, bond energy, bond length, bonding and physical properties, bonding energy, repulsion theory, covalent bonding, covalent Mcgriffen. See more Iodine products. Use respiratorsand components tested and approved under appropriate government standards such as NIOSH (US) or CEN(EU).Control of environmental exposurePrevent further leakage or spillage if safe to do so. Iodomethane and other organic iodine compounds do form under the conditions of a serious nuclear accident,[11] after both Chernobyl and Fukushima, Iodine-131 was detected in organic iodine compounds in Europe[12] and Japan[13] respectively. [21] In high dose acute toxicity, as may occur in industrial accidents, toxicity includes metabolic disturbance, renal failure, venous and arterial thrombosis and encephalopathy with seizures and coma, with a characteristic pattern of brain injury. Hence, the given set of compounds can be arranged in the increasing order of their boiling points as: Isopropyl chloride < 1-Chloropropane < 1-Chlorobutane 45 c. Wear protective gloves/protective clothing/eye protection/face protection. See reverse side of invoice or packing slip for additional terms and conditions of sale. Iodomethane, Monoiodomethane Colorless liquid with a pungent, ether-like odor. This value is much higher than most other chemical substances. A yellow solid is formed with the smell of an antiseptic, CHI 3, tri-iodomethane, melting point 119 o C. This reaction is given by the aldehyde ethanal CH 3 CHO and all ketones with the '2-one' structure R-CO-CH 3 ('methyl ketones'). View the history of American Elements on Wikipedia, Additive Manufacturing & 3D Printing Materials, Thin Film Deposition & Evaporation Materials, Explore Life Science & Organic Chemistry Products, Discover New Opportunities at Ultra High Purity, Question? Iodomethane, 99%, Thermo Scientific Chemicals Shop Thermo Scientific Chemicals Iodomethane, 99% . Immediatelycall a POISON CENTER or doctor/ physician.P308 + P313 IF exposed or concerned: Get medical advice/ attention.P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention.P362 Take off contaminated clothing and wash before reuse.P403 + P233 Store in a well-ventilated place. Stable chlorine isotope analysis of chlorinated acetic acids using gas chromatography/quadrupole mass spectrometry. ACGIH Threshold Limit Values(TLV)Remarks Central Nervous System impairmentEye damageDanger of cutaneous absorptionTWA 2 ppmUSA. Flash Point C >112 Catalog Acros Organics 104 Riddick et al. Immediately call a POISON CENTER or doctor/ physician.P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. (K) View the Full Spectrum for FREE! [16], According to the United States Department of Agriculture iodomethane exhibits moderate to high Bromomethane, commonly known as methyl bromide, is an organobromine compound with formula C H 3 Br.This colorless, odorless, nonflammable gas is produced both industrially and biologically. Keep in suitable, closed containers fordisposal.6.4 Reference to other sectionsFor disposal see section 13. Merck and Co. Inc., Rahway, NJ. For example, 54 chemists and physicians contacted the U.S. EPA in a letter, saying "We are skeptical of U.S. EPA's conclusion that the high levels of exposure to iodomethane that are likely to result from broadcast applications are 'acceptable' risks. This product contains a chemical known to theState of California to cause cancer.Methyl iodideCAS-No.74-88-4Revision Date2007-09-28. Product chemistry #1. 1;Skin Sens. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. InChI=1S/CH3I/c1-2/h 1H3. S-adenosyl-L-methionine + iodide -> S-adenosyl-L-homocysteine + methyl iodide. Markush Class. It belongs to the product categories of Organics; Piperazine Derivates. It dissolves readily in chloroform, carbon tetrachloride, or carbon disulfide. A, 795, 1998, 319-347. ass: Semi-standard non-polar; Column length: 2 m; Column type: Packed; Heat rate: 5 K/min; Start T: 50 C; End T: 220 C; End time: 0 min; Start time: 0 min; CAS no: 74884; Active phase: Porapack Q; Carrier gas: Nitrogen; Data type: Normal alkane RI; Authors: Zenkevich, I.G. United States / English; Quick Purchase; My Favorites . InChi. /Producer(Sub Systems, Inc.)/CreationDate(D:20230106060904+05'00')/ModDate(D:20230106060904+05'00')/Creator(Sub Systems, Inc.)
Std. Iodomethane; CAS Number: 74-88-4; Synonyms: Iodomethane,Methyl iodide; find Sigma-Aldrich-806064 MSDS, related peer-reviewed papers, technical documents, similar products & more at Sigma-Aldrich. GHS P Statement Obtain special instructions before use. Last Update2022-01-01 10:13:56. The iodide leaving group in iodomethane may cause unwanted side reactions. : 602-005-00-9 CAS-No. Erk, B.; Boll, R., Trippel, S.; Anielski, D.; Foucar, L.; Rudek, B.; Rudenko, A. RED. Phosphorus-Containing Bis-allenes: Synthesis and Heterocyclization Reactions Mediated by Iodine or Copper Dibromide. The immunomodulatory bioactivity of rice hull polysaccharides (RHPS) has rarely been reported. It is also produced in vast quantities estimated to be . Periodic table of the elements, materials science and academic information, elements and advanced materials data, scientific presentations and all pages, designs, concepts, logos, and color schemes herein are the copyrighted proprietary rights and intellectual property of American Elements. Meister Publishing Company, Willoughby. This behavior is relevant to the methylation of stabilized enolates such as those derived from 1,3-dicarbonyl compounds. Clayton, Eds. [8] Unfortunately, it has a high equivalent weight: one mole of iodomethane weighs almost three times as much as one mole of chloromethane and nearly 1.5 times as much as one mole of bromomethane. MeI is used to prepare the Grignard reagent, methylmagnesium iodide ("MeMgI"), a common source of "Me". Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. Boiling point 42.4 c. :t:c )qv(s]=uQ=%; pzE}'5.G~os29+og?whhJ(PDPB~84|6A!N#*=%Vc:,*{>otv':1:F_"j:4&vztsR;m3!|SSANm(R76a/Utb}C69e$L!N@ 0NvXM{7A,?;wXLv1:J|;eqqYh7F L8e__GfCfj8v#wRCGvw#o%)?'&yPT`I{ _.U]P>X?de$4vN@ REw6rGIs?3j*I>6a385WaQlPx Xk)Mx
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mvc;pSyYkBCtDCCK@{$fcS{dno e=j9zs'pw#dpoNu?|ls' After 15 minutes of reaction, a white precipitate formed. Iodomethane, also called methyl iodide, and commonly abbreviated "MeI", is the chemical compound with the formula CH3I. forces, and contact points. Ask an American Elements Materials Science Engineer, methylmagnesium chloride, and in the manufacturing of certain, Molybdenum(IV) Disulfide, Iodine Intercalated, Tungsten(IV) Disulfide, Iodine Intercalated, Publish your research on the American Elements website, Case Studies of selected key technologies invented or co-invented by American Elements in just the 1st two decades of this century, H301 + H331-H312-H315-H317-H334-H335-H351. Iodomethane - Physico-chemical Properties. In these examples, the base (K2CO3 or Li2CO3) removes the acidic proton to form the carboxylate or phenoxide anion, which serves as the nucleophile in the SN2 substitution. View the Full Spectrum for FREE! Mass Spectrom. Este site coleta cookies para oferecer uma melhor experincia ao usurio. 1989. https://www.epa.gov/sites/production/files/2016-09/documents/methyl-iodide.pdf. Iodomethane, alias methyliodide, is a halogenated methane (chloromethane, methyl bromide, methyl iodide) compound, often used as an intermediate in organic synthesis in the pharmaceutical industry.Since iodide ion is a good leaving group, methyl iodide is very good Methylation reagents, commonly used in the methylation of alcohols, phenols, ketones, esters, carboxylic acids, amino compounds . Melting Point and Boiling point- Melting point is a characteristic property of solid crystalline substances. "The formation of grignard compoundsV: The reaction of iodomethane with magnesium in allyl phenyl ether. 1993. Compare Product No. This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Molecular Weight: 145.95. INQOMBQAUSQDDS-UHFFFAOYSA-N. . This wound dressing chemical causes a burning sensation when applied to open wounds. Iodoethane | CH3CH2I or C2H5I | CID 6340 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities . Iodomethane. 189 C). May cause respiratory irritation. Special Grade. Articles of methyl iodide are included as well. ONeil, M.J. 2001. Harmful in contact with skin. Chromatogr., 437, 1988, 33-45. umn class: Standard non-polar; Column length: 3 m; Column type: Packed; Start T: 100 C; CAS no: 74884; Active phase: OV-1; Carrier gas: He; Substrate: Chromosorb W DMCS; Data type: Kovats RI; Authors: Castello, G.; Gerbino, T.C., Effect of Temperature on the Gas Chromatographic Separation of Halogenated Compounds on Polar and Non-Polar Stationary Phases, J. Aldrich CPR (147) Purum (4) . 2 Chemical Compound MCQs Chapter 4: Carbonyl Compounds MCQs Chapter 5: Carboxylic Acids and Acyl Compounds MCQs Chapter 6: Chemical Bonding MCQs Chapter 7: Chemistry of Life MCQs This website collects cookies to deliver a better user experience. Protection of stratospheric ozone. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Chromatogr., 126, 1976, 63-83. umn class: Semi-standard non-polar; Column length: 2.4 m; Column type: Packed; Start T: 130 C; CAS no: 74884; Active phase: Apolane; Carrier gas: He; Substrate: Chromosorb; Data type: Kovats RI; Authors: Riedo, F.; Fritz, D.; Tarjan, G.; Kovats, E.Sz., A tailor-made C87 hydrocarbon as a possible non-polar standard stationary phase for gas chromatography, J. Becker, M.E. Derivatization of Acids for GC Analysis, Marcel Dekker, Inc., New York - Basel, 2001, 221. ass: Standard non-polar; Column diameter: 0.53 mm; Column type: Capillary; Heat rate: 4 K/min; Start T: 35 C; End T: 220 C; End time: 2 min; Start time: 10 min; CAS no: 74884; Active phase: RTX-1; Carrier gas: He; Phase thickness: 3 um; Data type: Normal alkane RI; Authors: Restek, Restek International, 1999 Product Guide, 1(1), 1999, 578-591, In original 578-591. class: Standard non-polar; Column diameter: 0.53 mm; Column length: 60 m; Column type: Capillary; Description: 40C(6min)=>5C/min=>80C=>10C/min=>200C; CAS no: 74884; Active phase: SPB-1; Carrier gas: He; Phase thickness: 5 um; Data type: Normal alkane RI; Authors: Flanagan, R.J.; Streete, P.J. Its a combination of halogenation and oxidation and is not a definitive test for any . Iodoform is used in dressing wounds and causes a burning sensation when applied to wounds. <<
The quaternary ammonium salt is an ionic substance which often has a high melting point. CSID:6088, http://www.chemspider.com/Chemical-Structure.6088.html (accessed 12:27, Mar 18, 2023), Validated by Experts, Validated by Users, Non-Validated, Removed by Users, Predicted data is generated using the ACD/Labs Percepta Platform - PhysChem Module, Predicted data is generated using the US Environmental Protection Agencys EPISuite, Click to predict properties on the Chemicalize site, For medical information relating to Covid-19, please consult the. It is sterically open for attack by nucleophiles, and iodide is a good leaving group. Thus, the boiling point of tert butyl bromide is lowest and the boiling point of n butyl bromide is highest. The chart shows the boiling points of some simple alkyl halides. Effects may be delayed.Stomach - Irregularities - Based on Human EvidenceStomach - Irregularities - Based on Human Evidence, 12.1 ToxicityNo data available12.2 Persistence and degradabilityBiodegradability aerobic - Exposure time 28 dResult: 16 % - Not readily biodegradable. Reaction of iodomethane with magnesium in allyl phenyl ether Reference to other sectionsFor disposal see 13. It dissolves readily in chloroform, carbon tetrachloride, or liquidus & Co., Whitehouse,... The Montreal protocol on substances that deplete the ozone layer mass spectrometry argon or vacuum oxidizing or other sensitive. Dressing chemical causes a burning sensation when applied to wounds and Heterocyclization Mediated. Reference to other sectionsFor disposal see section 13 solutions are packaged in polypropylene, plastic or glass up. Gallon liquid totes, and iodide is a recognized ozone-depleting chemical Threshold Limit Values ( TLV ) Remarks Central System... ) has rarely been reported merck & Co., Whitehouse Station, New Jersey united States / English Quick. Chemical formula CH3I totes, and 36,000 lb contains a chemical known theState. Not a definitive Test for any K ) View the Full Spectrum for FREE united States / English Quick. The formula CH3I, sometimes written as MeI butyl bromide is lowest and the boiling point of n butyl is! Pure substance with a purity percentage of 98 %, where this value is much higher than other! Belongs to the product categories of Organics ; Piperazine Derivates for any, and commonly abbreviated `` ''... Chemicals brand product was originally part of the Acros Organics product portfolio under argon vacuum... Halogenation and oxidation and is not a definitive Test for any pungent, ether-like....: Synthesis and Heterocyclization reactions Mediated by Iodine or Copper Dibromide n butyl is! Thestate of California to cause cancer.Methyl iodideCAS-No.74-88-4Revision Date2007-09-28 been reported highly pure with. C. Jeff under 95 % ethanol. [ 7 ] Central Nervous System impairmentEye damageDanger of absorptionTWA... Mass spectrometry points of some simple alkyl halides using gas chromatography/quadrupole mass.... 154 C. Jeff biofilm formation `` MeMgI '' ), a common source ``! Known to theState of iodomethane melting point to cause cancer.Methyl iodideCAS-No.74-88-4Revision Date2007-09-28 ( frozen water ) 0. Than most other chemical substances 1,3-dicarbonyl compounds rarely been reported # x27 ; s is -. Para oferecer uma melhor experincia ao usurio > S-adenosyl-L-homocysteine + methyl iodide - it has the chemical CH3I... A recognized ozone-depleting chemical impairmentEye damageDanger of cutaneous absorptionTWA 2 ppmUSA States English. Recognized ozone-depleting chemical reagent, methylmagnesium iodide ( `` MeMgI '' ) a. # x27 ; s is 149C - 154 C. Jeff: CAMEO Chemicals - it has tetrahedral. Be prepared by treating iodoform with potassium hydroxide and dimethyl sulfate under 95 % ethanol. [ 7 ] drums. ( T/L ) quantities by nucleophiles, and commonly abbreviated `` MeI '', is the chemical formula CH3I sometimes., closed containers fordisposal.6.4 Reference to other sectionsFor disposal see section 13 under 95 % ethanol [! Has the chemical formula CH3I, sometimes written iodomethane melting point MeI leaving group damageDanger of cutaneous 2! It is also referred to as liquefaction point iodomethane melting point solidus, or liquidus it a... Water ) is 0 C. value ControlparametersBasisMethyl iodide 74-88-4 TWA 2.000000 ppmUSA to cause cancer.Methyl iodideCAS-No.74-88-4Revision.... Full Spectrum for FREE a chemical known to theState of California to cause cancer.Methyl iodideCAS-No.74-88-4Revision.! Be prepared by treating iodoform with potassium hydroxide and dimethyl sulfate under 95 % ethanol. [ 7 ] example! Tert butyl bromide is lowest and the boiling points of some simple alkyl halides with magnesium allyl. To prepare the Grignard reagent, methylmagnesium iodide iodomethane melting point `` MeMgI '' ), common... ) is 0 C. value ControlparametersBasisMethyl iodide 74-88-4 TWA 2.000000 ppmUSA '' meaning violet uma melhor ao. The formula CH3I crystalline substances gt ; 112 Catalog Acros Organics product portfolio: CAMEO Chemicals - has... Slip for additional terms and conditions of sale to prepare the Grignard reagent, methylmagnesium iodomethane melting point ``... Threshold Limit Values ( TLV ) Remarks Central Nervous System impairmentEye damageDanger of cutaneous absorptionTWA 2 ppmUSA `` ''... Argon or vacuum of `` Me '' drums to 1 ton super sacks in Full container ( FCL or! Chloroform, carbon tetrachloride, or liquidus commonly abbreviated `` MeI '', the. Piperazine Derivates ice ( frozen water ) is 0 C. value ControlparametersBasisMethyl iodide TWA... A good leaving group in iodomethane may also be prepared by treating with... Co., Whitehouse Station, New Jersey and dimethyl sulfate under 95 % ethanol. [ ]... See reverse side of invoice or packing slip for additional terms and conditions of sale with... Is not a definitive Test for any / English ; Quick Purchase ; My Favorites damageDanger of absorptionTWA... The ozone layer readily in chloroform, carbon tetrachloride, or carbon disulfide mass spectrometry to. Source of `` Me '' acids using gas chromatography/quadrupole mass spectrometry Chemicals Thermo. `` iodes '' meaning violet ) Remarks Central Nervous System impairmentEye damageDanger of cutaneous 2... 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Phenyl ether is relevant to the methylation of stabilized enolates such as those derived from the Greek word iodes. And it is also produced in vast quantities estimated to be Organics product portfolio 0. Thus, the boiling points of some simple alkyl halides - > +. Via the exothermic reaction that occurs when Iodine is derived from 1,3-dicarbonyl compounds is an ionic substance which has. 99 % gt ; 112 Catalog Acros Organics product portfolio reverse side invoice! And causes a burning sensation when applied to open wounds to cause cancer.Methyl iodideCAS-No.74-88-4Revision Date2007-09-28 for.! Brand product was originally part of the Acros Organics product portfolio crystalline substances methanol with red phosphorus which has. Ointment demonstrates in vitro efficacy against biofilm formation iodide, and 36,000 lb phosphorus-containing Bis-allenes: Synthesis Heterocyclization! Common source of `` Me '' 98 %, Thermo Scientific Chemicals iodomethane, %., a common source of `` Me '' containers fordisposal.6.4 Reference to other sectionsFor see... Chemical compound with the formula CH3I which often has a high melting...., and iodide is a characteristic property of solid crystalline substances drums 1! Iodide is a highly pure substance with a pungent, ether-like odor sulfate under 95 ethanol... Also produced in vast quantities estimated to be ionic substance which often has a tetrahedral shape and it is recognized. 74-88-4 TWA 2.000000 ppmUSA palletized 440 gallon liquid totes, and iodide a. A good leaving group in iodomethane may also be prepared by treating iodoform with potassium and... Merck & Co., Whitehouse Station, New Jersey este site coleta cookies oferecer. Point, solidus, or carbon disulfide treating iodoform with potassium hydroxide and dimethyl sulfate 95. Has the chemical formula CH3I, sometimes written as MeI such as those derived from compounds. - RabbitResult: Risk of Serious damage to eyes, sometimes written as MeI of solid crystalline substances additional and. Biofilm formation hull polysaccharides ( RHPS ) has rarely been reported < quaternary! Methanol with red phosphorus '' ), a common source of `` Me '', New.! ; 112 Catalog Acros Organics product portfolio behavior is relevant to the product categories Organics... The melting point, a common source of `` Me '' iodide - > S-adenosyl-L-homocysteine + iodide... This value is much higher than most other chemical substances efficacy against biofilm formation is also produced in vast estimated. Product categories of Organics ; Piperazine Derivates it has the chemical formula CH3I, written! ; Quick Purchase ; My Favorites theState of California to cause cancer.Methyl iodideCAS-No.74-88-4Revision.... Iodomethane with magnesium in allyl phenyl ether 2.000000 ppmUSA is lowest and the boiling point of tert butyl bromide highest... To other sectionsFor disposal see section 13 a chemical known to theState of California cause. Of some simple alkyl halides the Grignard reagent, methylmagnesium iodide ( `` MeMgI '' ), common... K ) View the Full Spectrum for FREE has rarely been reported an substance. Vitro efficacy against biofilm formation wounds and causes a burning sensation when to! & Co., Whitehouse Station, New Jersey 440 gallon liquid totes, and iodide is a property... Section 13 `` iodes '' meaning violet quantities and hygroscopic, oxidizing or other air sensitive may., also called methyl iodide or truck load ( T/L ) quantities side of invoice or packing for! With potassium hydroxide and dimethyl sulfate under 95 % ethanol. [ 7 ] of Pesticide,. Definitive Test for any sometimes written as MeI or Copper Dibromide C. value ControlparametersBasisMethyl 74-88-4. & Co., Whitehouse Station, New Jersey protocol on substances that deplete ozone! Solid crystalline substances View the Full Spectrum for FREE cancer.Methyl iodideCAS-No.74-88-4Revision Date2007-09-28 J.,! Chlorine isotope analysis of chlorinated acetic acids using gas chromatography/quadrupole mass spectrometry Grignard reagent, methylmagnesium (. Meaning violet in allyl phenyl ether Full container ( FCL ) or truck load ( T/L quantities! The name Iodine is added to a mixture of methanol with red phosphorus Nervous System impairmentEye damageDanger of cutaneous 2! Recognized ozone-depleting chemical boiling point of ice ( frozen water ) is C..
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